High-Temperature Synthesis Department

A novel synthesis method for AlB₁₂ has been developed and implemented, forming the basis for a semi-industrial technology to obtain submicron (100–150 nm), technically pure, single-phase aluminum dodecaboride powders.

Synthesis procedures have been elaborated, and the properties of the following composite systems have been studied:

AlB₁₂–AlN

synthesized across a wide range of concentrations; 100 % technological yield, no cracking defects, load resistance up to 500 N (Vickers test), high thermal conductivity and electromagnetic permeability

AlB₁₂C₂–Al₈B₄C₇

capability to form nano- and microsized particles, use of a liquid phase as a compaction activator, high hardness and fracture toughness

AlB₁₂–TiC

complete component interaction, exceptional mechanical strength, and fracture toughness up to 7–8 MPa•m¹ᐟ²

From these ceramics, laminated armor elements have been fabricated and have shown positive results in ballistic testing.

In addition, synthesis procedures have been developed and the properties of six boron-carbide-based ceramics (B₄C) have been investigated.

The introduction of specific additives enabled a reduction in hot-pressing temperature by 200–300 °C.

All synthesized ceramic composites demonstrate high mechanical performance:
Hardness

Hv = 24.1 GPa (at 49 N load)

Fracture toughness

K₁c = 3.67 ± 1.2 MPa·m¹ᐟ²

Flexural strength

Rᵦm = 285 MPa

Compressive strength

R𝑐s = 378 MPa

Porosity

P ≈ 0 at a specific density of γ = 2.5–3.0 g/cm³

💡 The developments of the High-Temperature Synthesis Department form the scientific and technological foundation for advanced heat-resistant, armor, and anti-radiation materials with promising applications in defense, aerospace, and high-performance industrial systems.

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